Hydrogen
Hydrogen is a chemical element that has the symbol H and an atomic number of 1. At standard temperature and pressure it is a colorless, odorless, nonmetallic, tasteless, highly flammable diatomic gas (H2). With an atomic mass of 1.00794 g/mol, hydrogen is the lightest element.
Hydrogen is the most abundant of the chemical elements, constituting roughly 75% of the universe's elemental mass. Stars in the main sequence are mainly composed of hydrogen in its plasma state. Elemental hydrogen is relatively rare on Earth, and is industrially produced from hydrocarbons such as methane, after which most elemental hydrogen is used "captively" (meaning locally at the production site), with the largest markets about equally divided between fossil fuel upgrading.
History
Discovery of H2
Hydrogen gas, H2, was first artificially produced and formally described by T. Von Hohenheim (also known as Paracelsus, 1493–1541) via the mixing of metals with strong acids. He was unaware that the flammable gas produced by this chemical reaction was a new chemical element. In 1671, Robert Boyle rediscovered and described the reaction between iron filings and dilute acids, which results in the production of hydrogen gas. In 1766, Henry Cavendish was the first to recognize hydrogen gas as a discrete substance, by identifying the gas from a metal-acid reaction as "inflammable air", and further finding that the gas produces water when burned. Cavendish had stumbled on hydrogen when experimenting with acids and mercury. Although he wrongly assumed that hydrogen was a liberated component of the mercury rather than the acid, he was still able to accurately describe several key properties of hydrogen. He is usually given credit for its discovery as an element. In 1783, Antoine Lavoisier gave the element the name of hydrogen when he (with Laplace) reproduced Cavendish's finding that water is produced when hydrogen is burned. Lavoisier's name for the gas won out.
One of the first uses of H2 was for balloons. The H2 was obtained by reacting sulphuric acid and metallic iron. Infamously, H2 was used in the Hindenburg airship that was destroyed in a midair fire.
Combustion
Hydrogen can combust rapidly in air. It burned rapidly in the Hindenburg disaster on May 6, 1937
Hydrogen gas is highly flammable and will burn at concentrations as low as 4% H2 in air. The enthalpy of combustion for hydrogen is –286 kJ/mol; it combusts according to the following balanced equation.
2 H2(g) + O2(g) → 2 H2O(l) + 572 kJ
When mixed with oxygen across a wide range of proportions, hydrogen explodes upon ignition. Hydrogen burns violently in air. Pure hydrogen-oxygen flames are nearly invisible to the naked eye, as illustrated by the faintness of flame from the main Space Shuttle engines (as opposed to the easily visible flames from the shuttle boosters). Thus it is difficult to visually detect if a hydrogen leak is burning. The Hindenburg zeppelin flames seen in the adjacent picture are hydrogen flames colored with material from the covering skin of the zeppelin which contained carbon and pyrophoric aluminium powder. (Regardless of the cause of this fire, this was clearly primarily a hydrogen fire since skin of the Zeppelin alone would have taken many hours to burn). Another characteristic of hydrogen fires is that the flames tend to ascend rapidly with the gas in air, as illustrated by the Hindenberg flames, causing less damage than hydrocarbon fires. For example, two-thirds of the Hindenburg passengers survived that hydrogen fire, and many of the deaths which occurred were from falling or from gasoline burns.
H2 reacts directly with other oxidizing elements. A violent and spontaneous reaction can occur at room temperature with chlorine and fluorine, forming the corresponding hydrogen halides: hydrogen chloride and hydrogen fluoride
This is my work on Hydrogen
1 comment:
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